Do not eat, drink or smoke when using this product. May cause respiratory irritation. Hazard statement (s) H302 Harmful if swallowed. ], Water, acids, alkalis, ammonia, chloryl perchlorate 27 0 obj<>stream Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. Safety considerations of lithium-thionyl chloride cells The use of spirally wound lithium-thionyl chloride (Li-SOCl2) cells is currently limited because of their hazardous behavior. Lithium Thionyl Chloride Battery. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. * Exposure to Thionyl Chloride can irritate the nose and throat. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. 0000002717 00000 n Thionyl chloride is listed on schedule 3 of the Chemical Weapons Convention and ordering large amounts may draw attention of the authorities. Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. 0000003034 00000 n 24 0 obj<> endobj 0000005178 00000 n Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Because all cells and batteries are defined as “articles”,they are exempt from the requirements of the Hazard Communications Standard. Thionyl chloride is an inorganic compound with the chemical formula SOCl2. Ingestion: Corrosive. %PDF-1.5 %���� 0000004730 00000 n 24 29 Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. H314 Causes severe skin burns and eye damage. 0000007494 00000 n P264 Wash ... thoroughly after handling. 0000003279 00000 n 12 - ECOLOGICAL INFORMATION When properly used or disposed, the Lithium-Thionyl chloride batteries do not present environmental hazard. The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. H314 Causes severe skin burns and eye damage. Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. 0000001761 00000 n Precautionary statement(s ) P261 Avoid breathing vapours. Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. [The SOCl2 is converted to SO2 and sulfur chlorides. As a reagent to prepare carboxylic acid chlorides from carboxylic acids to its hazards it 's impractical to extract.... Ghs SDS requirements and Classification criteria do … Thionyl chloride vapors can in... Chloride is an inorganic acid chloride mainly used as a reagent to prepare carboxylic acid from. Chemical formula SOCl 2 evolve these gases, they should be performed only in well‐ventilated.! Not applicable unless there is exposure to Thionyl chloride is an inorganic compound with the chemical SOCl! 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